Molecular Sieve 4A Safety Data Sheet
Posted by Mark McCullagh on
SECTION 1: IDENTIFICATION
1.1. Product Identifier
|
Product Form: Substance |
|
Product Name: Molecular Sieve 4A |
1.2. Intended Use of the Product
|
Use of the Substance/Mixture: Air purification and dehydration |
1.3. Name, Address, and Telephone of the Responsible Party
|
Company Alpha-Pure Corporation |
|
1.4. Emergency Telephone Number
|
Emergency Number |
: |
877-645-7676 |
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
GHS-US Classification
|
Carc. 1A |
H350 |
Full text of hazard classes and H-statements : see section 16
2.2. Label Elements
GHS-US Labeling
|
Hazard Pictograms (GHS-US) |
: |
GHS08 |
|
|
|
|
|
|
Signal Word (GHS-US) |
: |
Danger |
|||||
|
Hazard Statements (GHS-US) |
: |
H350 - May cause cancer. |
|||||
|
Precautionary Statements (GHS-US) |
: |
P201 - Obtain special instructions before use. |
|||||
2.3. Other Hazards
Exposure may aggravate pre-existing eye, skin, or respiratory conditions.
2.4. Unknown Acute Toxicity (GHS-US)
No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substance
|
Name |
: |
Molecular Sieve 4A |
|
|||
|
Name |
Product Identifier |
% |
GHS-US classification |
|||
|
Zeolite |
(CAS-No.) 1318-02-1 |
100 |
Not classified |
|||
|
Quartz |
(CAS-No.) 14808-60-7 |
< 1 |
Carc. 1A, H350 STOT SE 3, H335 STOT RE 1, H372 |
|||
Full text of H-phrases: see section 16
3.2. Mixture
Not applicable
SECTION 4: FIRST AID MEASURES
4.1. Description of First-aid Measures
|
First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). |
|
First-aid Measures After Inhalation: When symptoms occur: go into open air and ventilate suspected area. Obtain medical attention if breathing difficulty persists. |
|
First-aid Measures After Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 5 minutes. If exposed or concerned: Get medical advice/attention. |
|
First-aid Measures After Eye Contact: Rinse cautiously with water for at least 5 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if irritation develops or persists. |
|
First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain medical attention. |
4.2. Most Important Symptoms and Effects Both Acute and Delayed
|
Symptoms/Injuries: May cause cancer. Dust may cause mechanical irritation to eyes, nose, throat, and lungs. |
|
Symptoms/Injuries After Inhalation: Prolonged exposure may cause irritation. |
|
Symptoms/Injuries After Skin Contact: Prolonged exposure may cause skin irritation. |
|
Symptoms/Injuries After Eye Contact: May cause slight irritation to eyes. |
|
Symptoms/Injuries After Ingestion: Ingestion may cause adverse effects. |
|
Chronic Symptoms: May cause cancer. |
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed
If exposed or concerned, get medical advice and attention. If medical advice is needed, have product container or label at hand.
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
|
Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. |
|
Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. |
5.2. Special Hazards Arising From the Substance or Mixture
|
Fire Hazard: Product is not flammable. |
|
Explosion Hazard: Product is not explosive. |
|
Reactivity: Hazardous reactions will not occur under normal conditions. |
5.3. Advice for Firefighters
|
Precautionary Measures Fire: Exercise caution when fighting any chemical fire. |
|
Firefighting Instructions: Use water spray or fog for cooling exposed containers. |
|
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. |
|
Hazardous Combustion Products: None known. |
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
|
General Measures: Do not breathe dust. Do not get in eyes, on skin, or on clothing. Do not handle until all safety precautions have been read and understood. |
6.1.1. For Non-Emergency Personnel
|
Protective Equipment: Use appropriate personal protective equipment (PPE). |
|
Emergency Procedures: Evacuate unnecessary personnel. |
6.1.2. For Emergency Personnel
|
Protective Equipment: Equip cleanup crew with proper protection. |
|
Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. Ventilate area. |
6.2. Environmental Precautions
Prevent entry to sewers and public waters.
6.3. Methods and Materials for Containment and Cleaning Up
|
For Containment: Contain solid spills with appropriate barriers and prevent migration and entry into sewers or streams. |
|
Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Recover the product by vacuuming, shoveling or sweeping. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. |
6.4. Reference to Other Sections
See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
|
Precautions for Safe Handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Avoid prolonged contact with eyes, skin and clothing. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust. |
|
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. |
7.2. Conditions for Safe Storage, Including Any Incompatibilities
|
Technical Measures: Comply with applicable regulations. |
|
Storage Conditions: Keep container closed when not in use. Store in a dry, cool place. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Store locked up/in a secure area. |
|
Incompatible Materials: Strong acids, strong bases, chlorine trifluoride, ethylene oxide, halogenated hydrocarbon, oxygen difluoride, sodium nitrate, vinyl compounds. |
7.3. Specific End Use(s)
Air purification and dehydration
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), or OSHA (PEL).
|
Quartz (14808-60-7) |
||
|
USA ACGIH |
ACGIH TWA (mg/m³) |
0.025 mg/m³ (respirable particulate matter) |
|
USA ACGIH |
ACGIH chemical category |
A2 - Suspected Human Carcinogen |
|
USA NIOSH |
NIOSH REL (TWA) (mg/m³) |
0.05 mg/m³ (respirable dust) |
|
USA IDLH |
US IDLH (mg/m³) |
50 mg/m³ (respirable dust) |
|
USA OSHA |
OSHA PEL (TWA) (mg/m³) |
50 µg/m³ |
8.2. Exposure Controls
|
Appropriate Engineering Controls |
: |
Suitable eye/body wash equipment should be available in the vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed. |
|
Personal Protective Equipment |
: |
Gloves. Protective clothing. Protective goggles. Insufficient ventilation: wear respiratory protection.
|
|
Materials for Protective Clothing |
: |
Chemically resistant materials and fabrics. |
|
Hand Protection |
: |
Wear protective gloves. |
|
Eye and Face Protection |
: |
Chemical safety goggles. |
|
Skin and Body Protection |
: |
Wear suitable protective clothing. |
|
Respiratory Protection |
: |
If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. In case of inadequate ventilation, oxygen deficient atmosphere, or where exposure levels are not known wear approved respiratory protection. |
|
Other Information |
: |
When using, do not eat, drink or smoke. |
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
|
Physical State |
: |
Solid |
|
Appearance |
: |
No data available |
|
Odor |
: |
No data available |
|
Odor Threshold |
: |
No data available |
|
pH |
: |
No data available |
|
Evaporation Rate |
: |
No data available |
|
Melting Point |
: |
No data available |
|
Freezing Point |
: |
No data available |
|
Boiling Point |
: |
No data available |
|
Flash Point |
: |
No data available |
|
Auto-ignition Temperature |
: |
No data available |
|
Decomposition Temperature |
: |
No data available |
|
Flammability (solid, gas) |
: |
No data available |
|
Vapor Pressure |
: |
No data available |
|
Relative Vapor Density at 20°C |
: |
No data available |
|
Relative Density |
: |
No data available |
|
Solubility |
: |
No data available |
|
Partition Coefficient: N-Octanol/Water |
: |
No data available |
|
Viscosity |
: |
No data available |
9.2. Other Information No additional information available
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity: Hazardous reactions will not occur under normal conditions.
10.2. Chemical Stability: Stable under recommended handling and storage conditions (see section 7).
10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
10.4. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, and incompatible materials.
10.5. Incompatible Materials: Strong acids, strong bases, chlorine trifluoride, ethylene oxide, halogenated hydrocarbon, oxygen difluoride, sodium nitrate, vinyl compounds.
10.6. Hazardous Decomposition Products: None expected under normal conditions of use.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on Toxicological Effects
|
Acute Toxicity: Not classified |
|
|
Zeolite (1318-02-1) |
|
|
LD50 Oral Rat |
5000 mg/kg |
|
LD50 Dermal Rabbit |
> 2000 mg/kg |
|
Quartz (14808-60-7) |
|
|
LD50 Oral Rat |
> 5000 mg/kg |
|
LD50 Dermal Rat |
> 5000 mg/kg |
Skin Corrosion/Irritation: Not classified
Serious Eye Damage/Irritation: Not classified
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Carcinogenicity: May cause cancer.
|
Zeolite (1318-02-1) |
|
|
IARC group |
3 |
|
Quartz (14808-60-7) |
|
|
IARC group |
1 |
|
National Toxicology Program (NTP) Status |
Known Human Carcinogens. |
|
OSHA Hazard Communication Carcinogen List |
In OSHA Hazard Communication Carcinogen list. |
|
Reproductive Toxicity: Not classified |
|
Specific Target Organ Toxicity (Single Exposure): Not classified |
|
Specific Target Organ Toxicity (Repeated Exposure): Not classified |
|
Aspiration Hazard: Not classified |
|
Symptoms/Injuries After Inhalation: Prolonged exposure may cause irritation. |
|
Symptoms/Injuries After Skin Contact: Prolonged exposure may cause skin irritation. |
|
Symptoms/Injuries After Eye Contact: May cause slight irritation to eyes. |
|
Symptoms/Injuries After Ingestion: Ingestion may cause adverse effects. |
|
Chronic Symptoms: May cause cancer. |
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
|
Ecology - General |
: |
Not classified. |
|
|
Zeolite (1318-02-1) |
|||
|
LC50 Fish 1 |
1800 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [semi-static]) |
||
|
EC50 Daphnia 1 |
1000 - 1800 mg/l (Exposure time: 48 h - Species: Daphnia magna) |
||
|
LC50 Fish 2 |
3200 - 5600 mg/l (Exposure time: 96 h - Species: Oryzias latipes [semi-static]) |
||
12.2. Persistence and Degradability
|
Molecular Sieve 4A |
|
|
Persistence and Degradability |
Not established. |
12.3. Bioaccumulative Potential
|
Molecular Sieve 4A |
|
|
Bioaccumulative Potential |
Not established. |
12.4. Mobility in Soil No additional information available
12.5. Other Adverse Effects
|
Other Information |
: |
Avoid release to the environment. |
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste Treatment Methods
|
Waste Disposal Recommendations: Dispose of contents/container in accordance with local, regional, national, and international regulations. |
|
Additional Information: Container may remain hazardous when empty. Continue to observe all precautions. |
|
Ecology - Waste Materials: Avoid release to the environment. |
SECTION 14: TRANSPORT INFORMATION
The shipping description(s) stated herein were prepared in accordance with certain assumptions at the time the SDS was authored, and can vary based on a number of variables that may or may not have been known at the time the SDS was issued.
14.1. In Accordance with DOT Not regulated for transport
14.2. In Accordance with IMDG Not regulated for transport
14.3. In Accordance with IATA Not regulated for transport
SECTION 15: REGULATORY INFORMATION
15.1. US Federal Regulations
|
Molecular Sieve 4A |
|
|
SARA Section 311/312 Hazard Classes |
Delayed (chronic) health hazard |
|
Quartz (14808-60-7) |
|
Listed on the United States TSCA (Toxic Substances Control Act) inventory |
15.2. US State Regulations
|
Quartz (14808-60-7) |
|
U.S. - Massachusetts - Right To Know List |
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
|
Date of Preparation or Latest Revision |
: |
12/14/2017 |
|
Other Information |
: |
This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 |
|
GHS Full Text Phrases: |
||
|
|
Carc. 1A |
Carcinogenicity Category 1A |
|
|
STOT RE 1 |
Specific target organ toxicity (repeated exposure) Category 1 |
|
|
STOT SE 3 |
Specific target organ toxicity (single exposure) Category 3 |
|
|
H335 |
May cause respiratory irritation |
|
|
H350 |
May cause cancer |
|
|
H372 |
Causes damage to organs through prolonged or repeated exposure |
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
SDS US (GHS HazCom)
Share this post
- Tags: MSDS