Molecular Sieve 4A Safety Data Sheet

MSDS info inside
Tuesday, March 6, 2018

According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Date of Issue:  12/14/2017
Version: 1.0

 

SECTION 1: IDENTIFICATION

1.1.       Product Identifier 

Product Form: Substance 

Product Name: Molecular Sieve 4A

1.2.       Intended Use of the Product  

Use of the Substance/Mixture: Air purification and dehydration

1.3.       Name, Address, and Telephone of the Responsible Party

Company  

Alpha-Pure Corporation
P.O. Box 471229
Charlotte, NC, USA
877-645-7676

 

1.4.       Emergency Telephone Number 

Emergency Number

:

877-645-7676

 

SECTION 2: HAZARDS IDENTIFICATION

2.1.       Classification of the Substance or Mixture

GHS-US Classification

Carc. 1A

H350

Full text of hazard classes and H-statements : see section 16

2.2.       Label Elements

GHS-US Labeling

Hazard Pictograms (GHS-US)

:

Hazard Pictograms (GHS-US) GHS08

GHS08

 

 

 

 

 

Signal Word (GHS-US)

:

Danger

Hazard Statements (GHS-US)

:

H350 - May cause cancer.

Precautionary Statements (GHS-US)

:

P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P280 - Wear protective gloves, protective clothing, and eye protection.
P308+P313 - If exposed or concerned: Get medical advice/attention.
P405 - Store locked up.
P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations.

2.3.       Other Hazards 

Exposure may aggravate pre-existing eye, skin, or respiratory conditions.  

2.4.       Unknown Acute Toxicity (GHS-US)

No data available

 

 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1.       Substance

Name

:

Molecular Sieve 4A

 

Name

Product Identifier

%

GHS-US classification

Zeolite

(CAS-No.) 1318-02-1

100

Not classified

Quartz

(CAS-No.) 14808-60-7

< 1

Carc. 1A, H350

STOT SE 3, H335

STOT RE 1, H372

             

Full text of H-phrases: see section 16

3.2.       Mixture

Not applicable

 

 

SECTION 4: FIRST AID MEASURES

4.1.       Description of First-aid Measures  

First-aid Measures General:  Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

First-aid Measures After Inhalation:  When symptoms occur: go into open air and ventilate suspected area. Obtain medical attention if breathing difficulty persists.

First-aid Measures After Skin Contact:  Remove contaminated clothing. Drench affected area with water for at least 5 minutes. If exposed or concerned: Get medical advice/attention.

First-aid Measures After Eye Contact:  Rinse cautiously with water for at least 5 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if irritation develops or persists.

First-aid Measures After Ingestion:  Rinse mouth. Do NOT induce vomiting. Obtain medical attention.

4.2.       Most Important Symptoms and Effects Both Acute and Delayed 

Symptoms/Injuries:  May cause cancer. Dust may cause mechanical irritation to eyes, nose, throat, and lungs. 

Symptoms/Injuries After Inhalation:  Prolonged exposure may cause irritation. 

Symptoms/Injuries After Skin Contact:  Prolonged exposure may cause skin irritation. 

Symptoms/Injuries After Eye Contact:  May cause slight irritation to eyes. 

Symptoms/Injuries After Ingestion:  Ingestion may cause adverse effects. 

Chronic Symptoms:  May cause cancer. 

4.3.       Indication of Any Immediate Medical Attention and Special Treatment Needed  

If exposed or concerned, get medical advice and attention. If medical advice is needed, have product container or label at hand.

 

 

SECTION 5: FIRE-FIGHTING MEASURES

5.1.       Extinguishing Media 

Suitable Extinguishing Media:  Use extinguishing media appropriate for surrounding fire. 

Unsuitable Extinguishing Media:  Do not use a heavy water stream. Use of heavy stream of water may spread fire. 

5.2.       Special Hazards Arising From the Substance or Mixture 

Fire Hazard:  Product is not flammable. 

Explosion Hazard:  Product is not explosive. 

Reactivity:  Hazardous reactions will not occur under normal conditions. 

5.3.       Advice for Firefighters 

Precautionary Measures Fire:  Exercise caution when fighting any chemical fire. 

Firefighting Instructions:  Use water spray or fog for cooling exposed containers. 

Protection During Firefighting:  Do not enter fire area without proper protective equipment, including respiratory protection. 

Hazardous Combustion Products:  None known.

 

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1.       Personal Precautions, Protective Equipment and Emergency Procedures

General Measures:  Do not breathe dust. Do not get in eyes, on skin, or on clothing. Do not handle until all safety precautions have been read and understood.

6.1.1.      For Non-Emergency Personnel 

Protective Equipment:  Use appropriate personal protective equipment (PPE). 

Emergency Procedures:  Evacuate unnecessary personnel. 

6.1.2.      For Emergency Personnel 

Protective Equipment:  Equip cleanup crew with proper protection. 

Emergency Procedures:  Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. Ventilate area. 

6.2.       Environmental Precautions 

Prevent entry to sewers and public waters.

6.3.       Methods and Materials for Containment and Cleaning Up 

For Containment:  Contain solid spills with appropriate barriers and prevent migration and entry into sewers or streams. 

Methods for Cleaning Up:  Clean up spills immediately and dispose of waste safely. Recover the product by vacuuming, shoveling or sweeping. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. 

6.4.       Reference to Other Sections 

 

See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations.

 

SECTION 7: HANDLING AND STORAGE

7.1.       Precautions for Safe Handling 

Precautions for Safe Handling:  Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Avoid prolonged contact with eyes, skin and clothing. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust. 

Hygiene Measures:  Handle in accordance with good industrial hygiene and safety procedures. 

7.2.       Conditions for Safe Storage, Including Any Incompatibilities 

Technical Measures:  Comply with applicable regulations. 

Storage Conditions:  Keep container closed when not in use. Store in a dry, cool place. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Store locked up/in a secure area. 

Incompatible Materials:  Strong acids, strong bases, chlorine trifluoride, ethylene oxide, halogenated hydrocarbon, oxygen difluoride, sodium nitrate, vinyl compounds. 

7.3.       Specific End Use(s) 

Air purification and dehydration  

 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1.       Control Parameters

For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), or OSHA (PEL).

Quartz (14808-60-7) 

USA ACGIH

ACGIH TWA (mg/m³)

0.025 mg/m³ (respirable particulate matter)

USA ACGIH

ACGIH chemical category

A2 - Suspected Human Carcinogen

USA NIOSH

NIOSH REL (TWA) (mg/m³)

0.05 mg/m³ (respirable dust)

USA IDLH

US IDLH (mg/m³)

50 mg/m³ (respirable dust)

USA OSHA

OSHA PEL (TWA) (mg/m³)

50 µg/m³

8.2.       Exposure Controls 

Appropriate Engineering Controls

:

Suitable eye/body wash equipment should be available in the vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed.

Personal Protective Equipment

:

Gloves. Protective clothing. Protective goggles. Insufficient ventilation: wear respiratory protection.

MSDS Gloves Protective Clothing Goggles Ventilation Mask

Materials for Protective Clothing

:

Chemically resistant materials and fabrics.

Hand Protection

:

Wear protective gloves.

Eye and Face Protection

:

Chemical safety goggles.

Skin and Body Protection

:

Wear suitable protective clothing.

Respiratory Protection

:

If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. In case of inadequate ventilation, oxygen deficient atmosphere, or where exposure levels are not known wear approved respiratory protection.

Other Information

:

When using, do not eat, drink or smoke.

 

 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1.       Information on Basic Physical and Chemical Properties

Physical State

:

Solid

Appearance

:

No data available 

Odor

:

No data available

Odor Threshold

:

No data available

pH

:

No data available

Evaporation Rate

:

No data available

Melting Point

:

No data available

Freezing Point

:

No data available

Boiling Point

:

No data available

Flash Point

:

No data available

Auto-ignition Temperature

:

No data available

Decomposition Temperature

:

No data available

Flammability (solid, gas)

:

No data available

Vapor Pressure

:

No data available

Relative Vapor Density at 20°C

:

No data available

Relative Density

:

No data available

Solubility

:

No data available

Partition Coefficient: N-Octanol/Water

:

No data available

Viscosity

:

No data available  

9.2.       Other Information  No additional information available

 

 

SECTION 10: STABILITY AND REACTIVITY

10.1.       Reactivity:    Hazardous reactions will not occur under normal conditions.

10.2.       Chemical Stability:    Stable under recommended handling and storage conditions (see section 7).

10.3.       Possibility of Hazardous Reactions:    Hazardous polymerization will not occur.

10.4.       Conditions to Avoid:    Direct sunlight, extremely high or low temperatures, and incompatible materials.

10.5.       Incompatible Materials:    Strong acids, strong bases, chlorine trifluoride, ethylene oxide, halogenated hydrocarbon, oxygen difluoride, sodium nitrate, vinyl compounds.

10.6.       Hazardous Decomposition Products:    None expected under normal conditions of use.

 

 

SECTION 11: TOXICOLOGICAL INFORMATION

11.1.       Information on Toxicological Effects

Acute Toxicity: Not classified 

Zeolite (1318-02-1)

LD50 Oral Rat

5000 mg/kg

LD50 Dermal Rabbit

> 2000 mg/kg

Quartz (14808-60-7)

LD50 Oral Rat

> 5000 mg/kg

LD50 Dermal Rat

> 5000 mg/kg

Skin Corrosion/Irritation: Not classified

Serious Eye Damage/Irritation: Not classified

Respiratory or Skin Sensitization: Not classified

Germ Cell Mutagenicity: Not classified

Carcinogenicity: May cause cancer.

Zeolite (1318-02-1)

IARC group

3

Quartz (14808-60-7)

IARC group

1

National Toxicology Program (NTP) Status

Known Human Carcinogens.

OSHA Hazard Communication Carcinogen List

In OSHA Hazard Communication Carcinogen list.

Reproductive Toxicity: Not classified

Specific Target Organ Toxicity (Single Exposure): Not classified

Specific Target Organ Toxicity (Repeated Exposure): Not classified

Aspiration Hazard: Not classified

Symptoms/Injuries After Inhalation: Prolonged exposure may cause irritation.

Symptoms/Injuries After Skin Contact: Prolonged exposure may cause skin irritation.

Symptoms/Injuries After Eye Contact: May cause slight irritation to eyes.

Symptoms/Injuries After Ingestion: Ingestion may cause adverse effects.

Chronic Symptoms: May cause cancer.

 

 

SECTION 12: ECOLOGICAL INFORMATION

12.1.       Toxicity 

Ecology - General

:

Not classified.

Zeolite (1318-02-1)

LC50 Fish 1

1800 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [semi-static])

EC50 Daphnia 1

1000 - 1800 mg/l (Exposure time: 48 h - Species: Daphnia magna)

LC50 Fish 2

3200 - 5600 mg/l (Exposure time: 96 h - Species: Oryzias latipes [semi-static])

12.2.       Persistence and Degradability 

Molecular Sieve 4A

Persistence and Degradability

Not established.

12.3.       Bioaccumulative Potential 

Molecular Sieve 4A

Bioaccumulative Potential

Not established.

12.4.       Mobility in Soil  No additional information available

12.5.       Other Adverse Effects

Other Information

:

Avoid release to the environment.

 

 

SECTION 13: DISPOSAL CONSIDERATIONS

13.1.       Waste Treatment Methods 

Waste Disposal Recommendations:  Dispose of contents/container in accordance with local, regional, national, and international regulations. 

Additional Information:  Container may remain hazardous when empty. Continue to observe all precautions. 

Ecology - Waste Materials:  Avoid release to the environment. 

 

 

SECTION 14: TRANSPORT INFORMATION

The shipping description(s) stated herein were prepared in accordance with certain assumptions at the time the SDS was authored, and can vary based on a number of variables that may or may not have been known at the time the SDS was issued.

14.1.       In Accordance with DOT       Not regulated for transport

14.2.       In Accordance with IMDG    Not regulated for transport

14.3.       In Accordance with IATA      Not regulated for transport

 

 

SECTION 15: REGULATORY INFORMATION

15.1.       US Federal Regulations 

Molecular Sieve 4A

SARA Section 311/312 Hazard Classes

Delayed (chronic) health hazard

Quartz (14808-60-7)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

 

15.2.       US State Regulations 

Quartz (14808-60-7)

U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List

 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION

Date of Preparation or Latest Revision

:

12/14/2017

Other Information

:

This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200

 

GHS Full Text Phrases:

 

Carc. 1A

Carcinogenicity Category 1A

 

STOT RE 1

Specific target organ toxicity (repeated exposure) Category 1

 

STOT SE 3

Specific target organ toxicity (single exposure) Category 3

 

H335

May cause respiratory irritation

 

H350

May cause cancer

 

H372

Causes damage to organs through prolonged or repeated exposure

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

SDS US (GHS HazCom)

 

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